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Filters: Author is Martin Trinh  [Clear All Filters]
2022
Mendez, M.; Trinh, M.; Miller, E.; Lin, D.; Sutton, R. 2022. PFAS in San Francisco Bay Water. SFEI Contribution No. 1094. San Francisco Estuary Institute: Richmond, CA.

Per- and polyfluoroalkyl substances (PFAS), a family of thousands of synthetic, fluorine-rich compounds commonly referred to as “forever chemicals,” are known for their thermal stability, non-reactivity, and surfactant properties. These unique compounds have widespread uses across consumer, commercial, and industrial products, resulting in widespread occurrence in the environment and wildlife across the globe. This study analyzed ambient surface water in San Francisco Bay for 40 PFAS to discern the occurrence, fate, and potential risks to ecological and human health.

Eleven of 40 PFAS were detected in ambient surface water collected in 2021 from 22 sites in the Bay. Seven PFAS (PFPeA, PFHxA, PFHpA, PFOA, PFBS, PFHxS, and PFOS), were found in at least 50% of samples. PFHxA and PFOA were the most frequently detected analytes (detection frequencies of 86% and 77%, respectively). PFPeA and PFHxA were generally found at the highest concentrations across sites, with median and maximum concentrations of 1.6 and 4.8 ng/L and 1.5 and 5.7 ng/L, respectively. Pairwise Spearman's correlations revealed strong positive correlations  (p <0.001; r > 0.77) among the seven PFAS detected in at least 50% of sites, suggesting significant similarities between their sources, pathways, and/or fate in the environment. PFBA, PFNA, PFDA, and 6:2 FTS were found at a limited number of sites in the Bay. 6:2 FTS was found at a single site at 14 ng/L, the highest concentration of any individual PFAS in the Bay. The sums of detected PFAS for all sites had median and maximum concentrations of 10 and 29 ng/L, respectively.

 (2.37 MB)
2023
Kleckner, A.; Sutton, R.; Yee, D.; Gilbreath, A.; Trinh, M. 2023. Water Year 2023 RMP Near-Field Water Sampling and Analysis Plan. SFEI Contribution No. 1142. San Francisco Estuary Institute: Richmond, CA.

This report details plans associated with the pilot near-field water sampling for the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP). The RMP recently reviewed the Status & Trends (S&T) Program and added a pilot effort to quantify contaminants of emerging concern (CECs) in Bay water in areas near (“near-field” of) expected loading pathways during or shortly after storm events and during the dry season. For the first year of the pilot (Water Year 2022), the near-field design included three targeted, near-field stations and four ambient Bay stations. Subsequent years added a fourth near-field station. Samples will be collected at these stations during or shortly after two storm events, and once in the dry season. The analytes that are being measured include bisphenols, organophosphate esters (OPEs), PFAS, and a suite of stormwater CECs.

 (13.36 MB)
2024
Trinh, M. 2024. 2021 Update to Copper Rolling Average. SFEI Contribution No. 1164. San Francisco Estuary Institute: Richmond, CA.
 (556.45 KB)
Trinh, M. 2024. 2021 Update to Cyanide Rolling Averages. San Francisco Estuary Institute: Richmond, CA.
 (552.88 KB)
Dougherty, J.; Kleckner, A.; Sutton, R.; Yee, D.; Gilbreath, A.; Trinh, M. 2024. Water Year 2024 RMP Near-Field Water Sampling and Analysis Plan. SFEI Contribution No. 1154.

This report details sampling and analysis plans associated with the pilot near-field water sampling for the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP). The RMP added a pilot effort to the  Status & Trends (S&T) Program to quantify contaminants of emerging concern (CECs) in Bay water in areas near (“near-field” of) expected loading pathways during or shortly after storm events and during the dry season. For the first year of the pilot (Water Year 2022), the near-field design included three targeted, near-field stations and four ambient Bay stations. A fourth near-field station was added in subsequent years. Samples are collected at these stations during or shortly after two storm events, and once in the dry season. The analytes being measured include bisphenols, organophosphate esters (OPEs), PFAS-target, PFAS-TOP, and a suite of stormwater CECs.

 (12.85 MB)