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Journal Article (Peer-Reviewed)
Aqueous Speciation and 1-Octanol-Water Partitioning of Tributyl- and Triphenyltin: Effect of pH and Ion Composition. Environmental Science and Technology 31 (9), 2596-2602.1997.
The Cloudwater Chemistry of Iron and Copper at Great Dun Fell, U.K. Atmospheric Environment 31 (16), 2515-2526.1997.
Declines in Polybrominated Diphenyl Ether Contamination of San Francisco Bay following Production Phase-Outs and Bans. Environmental Science and Technology 49 (2), 777-784 . SFEI Contribution No. 742.2015.
The Great Dun Fell Cloud Experiment 1993: An Overview. Atmospheric Environment 31 (16), 2393-2405.1997.
Methods Matter: Methods for Sampling Microplastic and Other Anthropogenic Particles and Their Implications for Monitoring and Ecological Risk Assessment. Integrated Environmental Assessment and Management 16 (6) . SFEI Contribution No. 1014.2020.
To inform mitigation strategies and understand how microplastics affect wildlife, research is focused on understanding the sources, pathways, and occurrence of microplastics in the environment and in wildlife. Microplastics research entails counting and characterizing microplastics in nature, which is a labor‐intensive process, particularly given the range of particle sizes and morphologies present within this diverse class of contaminants. Thus, it is crucial to determine appropriate sampling methods that best capture the types and quantities of microplastics relevant to inform the questions and objectives at hand. It is also critical to follow protocols with strict quality assurance and quality control (QA/QC) measures so that results reflect accurate estimates of microplastic contamination. Here, we assess different sampling procedures and QA/QC strategies to inform best practices for future environmental monitoring and assessments of exposure. We compare microplastic abundance and characteristics in surface‐water samples collected using different methods (i.e., manta and bulk water) at the same sites, as well as duplicate samples for each method taken at the same site and approximate time. Samples were collected from 9 sampling sites within San Francisco Bay, California, USA, using 3 different sampling methods: 1) manta trawl (manta), 2) 1‐L grab (grab), and 3) 10‐L bulk water filtered in situ (pump). Bulk water sampling methods (both grab and pump) captured more microplastics within the smaller size range (<335 μm), most of which were fibers. Manta samples captured a greater diversity of morphologies but underestimated smaller‐sized particles. Inspection of pump samples revealed high numbers of particles from procedural contamination, stressing the need for robust QA/QC, including sampling and analyzing laboratory blanks, field blanks, and duplicates. Choosing the appropriate sampling method, combined with rigorous, standardized QA/QC practices, is essential for the future of microplastics research in marine and freshwater ecosystems.
Multi-box mass balance model of PFOA and PFOS in different regions of San Francisco Bay. Chemosphere 252 . SFEI Contribution No. 986.2020.
We present a model to predict the long-term distribution and concentrations of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) in estuaries comprising multiple intercommunicated sub-embayments. To that end, a mass balance model including rate constants and time-varying water inputs was designed to calculate levels of these compounds in water and sediment for every sub-embayment. Subsequently, outflows and tidal water exchanges were used to interconnect the different regions of the estuary. To calculate plausible risks to population, outputs of the model were used as inputs in a previously designed model to simulate concentrations of PFOA and PFOS in a sport fish species (Cymatogaster aggregata). The performance of the model was evaluated by applying it to the specific case of San Francisco Bay, (California, USA), using 2009 sediment and water sampled concentrations of PFOA and PFOS in North, Central and South regions. Concentrations of these compounds in the Bay displayed exponential decreasing trends, but with different shapes depending on region, compound, and compartment assessed. Nearly stable PFOA concentrations were reached after 50 years, while PFOS needed close to 500 years to stabilize in sediment and fish. Afterwards, concentrations stabilize between 4 and 23 pg/g in sediment, between 0.02 and 44 pg/L in water, and between 7 and 104 pg/g wet weight in fish, depending on compound and region. South Bay had the greatest final concentrations of pollutants, regardless of compartment. Fish consumption is safe for most scenarios, but due to model uncertainty, limitations in monthly intake could be established for North and South Bay catches.
Per- and polyfluoroalkyl substances (PFAS) in San Francisco Bay wildlife: Temporal trends, exposure pathways, and notable presence of precursor compounds. Chemosphere 185, 1217-1226 . SFEI Contribution No. 839.2017.
Perfluoroalkyl compounds (PFCs) in wildlife from an urban estuary. Journal of Environmental Monitoring 14, 146-154.2012.
Poly- and perfluoroalkyl substances in wastewater: Significance of unknown precursors, manufacturing shifts, and likely AFFF impacts. Water Research . SFEI Contribution No. 780.2016.
In late 2014, wastewater effluent samples were collected from eight treatment plants that discharge to San Francisco (SF) Bay in order to assess poly- and perfluoroalkyl substances (PFASs) currently released from municipal and industrial sources. In addition to direct measurement of twenty specific PFAS analytes, the total concentration of perfluoroalkyl acid (PFAA) precursors was also indirectly measured by adapting a previously developed oxidation assay. Effluent from six municipal treatment plants contained similar amounts of total PFASs, with highest median concentrations of PFHxA (24 ng/L), followed by PFOA (23 ng/L), PFBA (19 ng/L), and PFOS (15 ng/L). Compared to SF Bay municipal wastewater samples collected in 2009, the short chain perfluorinated carboxylates PFBA and PFHxA rose significantly in concentration. Effluent samples from two treatment plants contained much higher levels of PFASs: over two samplings, wastewater from one municipal plant contained an average of 420 ng/L PFOS and wastewater from an airport industrial treatment plant contained 560 ng/L PFOS, 390 ng/L 6:2 FtS, 570 ng/L PFPeA, and 500 ng/L PFHxA. The elevated levels observed in effluent samples from these two plants are likely related to aqueous film forming foam (AFFF) sources impacting their influent; PFASs attributable to both current use and discontinued AFFF formulations were observed. Indirectly measured PFAA precursor compounds accounted for 33%–63% of the total molar concentration of PFASs across all effluent samples and the PFAA precursors indicated by the oxidation assay were predominately short-chained. PFAS levels in SF Bay effluent samples reflect the manufacturing shifts towards shorter chained PFASs while also demonstrating significant impacts from localized usage of AFFF.
Recommended Best Practices for Collecting, Analyzing, and Reporting Microplastics in Environmental Media: Lessons Learned from Comprehensive Monitoring of San Francisco Bay. Journal of Hazardous Materials . SFEI Contribution No. 1023.2020.
Microplastics are ubiquitous and persistent contaminants in the ocean and a pervasive and preventable threat to the health of marine ecosystems. Microplastics come in a wide variety of shapes, sizes, and plastic types, each with unique physical and chemical properties and toxicological impacts. Understanding the magnitude of the microplastic problem and determining the highest priorities for mitigation require accurate measures of microplastic occurrence in the environment and identification of likely sources. The field of microplastic pollution is in its infancy, and there are not yet widely accepted standards for sample collection, laboratory analyses, quality assurance/quality control (QA/QC), or reporting of microplastics in environmental samples. Based on a comprehensive assessment of microplastics in San Francisco Bay water, sediment, fish, bivalves, stormwater, and wastewater effluent, we developed recommended best practices for collecting, analyzing, and reporting microplastics in environmental media. We recommend factors to consider in microplastic study design, particularly in regard to site selection and sampling methods. We also highlight the need for standard QA/QC practices such as collection of field and laboratory blanks, use of methods beyond microscopy to identify particle composition, and standardized reporting practices, including suggested vocabulary for particle classification.
The Regional Monitoring Program for Water Quality in San Francisco Bay, California, USA: Science in support of managing water quality. Regional Studies in Marine Science 4.2016.
The Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) is a novel partnership between regulatory agencies and the regulated community to provide the scientific foundation to manage water quality in the largest Pacific estuary in the Americas. The RMP monitors water quality, sediment quality and bioaccumulation of priority pollutants in fish, bivalves and birds. To improve monitoring measurements or the interpretation of data, the RMP also regularly funds special studies. The success of the RMP stems from collaborative governance, clear objectives, and long-term institutional and monetary commitments. Over the past 22 years, high quality data and special studies from the RMP have guided dozens of important decisions about Bay water quality management. Moreover, the governing structure and the collaborative nature of the RMP have created an environment that allowed it to stay relevant as new issues emerged. With diverse participation, a foundation in scientific principles and a continual commitment to adaptation, the RMP is a model water quality monitoring program. This paper describes the characteristics of the RMP that have allowed it to grow and adapt over two decades and some of the ways in which it has influenced water quality management decisions for this important ecosystem.
Synthesis of long-term nickel monitoring in San Francisco Bay. Environmental Research 105, 20-33.2007.
Estuary News RMP Insert 2007. Estuary News.2007.
2010 Annual Monitoring Results. San Francisco Estuary Institute: Richmond, CA.2012.
Contaminants of Emerging Concern in San Francisco Bay: A Strategy for Future Investigations. 2015 Update. Contaminants of Emerging Concern in San Francisco Bay: A Strategy for Future Investigations. SFEI Contribution No. 761. San Francisco Estuary Institute: Richmond, CA.2015.
About this Update
The Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) has been investigating contaminants of emerging concern (CECs) since 2001. CECs can be broadly defined as synthetic or naturally occurring chemicals that are not regulated or commonly monitored in the environment but have the potential to enter the environment and cause adverse ecological or human health impacts.
The RMP Emerging Contaminants Workgroup (ECWG), established in 2006, includes representatives from RMP stakeholder groups, regional scientists, and an advisory panel of expert researchers that work together to address the workgroup’s guiding management question – Which CECs have the potential to adversely impact beneficial uses in San Francisco Bay? The overarching goal of the ECWG is to develop cost-effective strategies to identify and monitor CECs to minimize impacts to the Bay.
To this end, the RMP published a CEC Strategy document in 2013 (Sutton et al. 2013). The strategy is a living document that guides RMP special studies on CECs, assuring continued focus on the issues of highest priority to the health of the Bay. A key focus of the strategy is a tiered risk and management action framework that guides future monitoring proposals. The strategy also features a multi-year plan indicating potential future research priorities.
This 2015 CEC strategy update features revised designations of CECs in the tiered risk and management action framework based on monitoring and research conducted since 2013. Brief summaries of relevant RMP findings are provided. In addition, a proposed multi-year plan for future RMP Special Studies on CECs is outlined. A full revision of the CEC strategy is anticipated in 2016.
Contaminants of Emerging Concern in San Francisco Bay: A Strategy for Future Investigations 2018 Update. SFEI Contribution No. 873. San Francisco Estuary Institute: Richmond, CA.2018.
Contaminants of Emerging Concern in San Francisco Bay: A Strategy for Future Investigations. 2017 Revision. SFEI Contribution No. 815. San Francisco Estuary Institute: Richmond, CA.2017.
Contaminants of Emerging Concern in San Francisco Bay: A Strategy for Future Investigations. San Francisco Estuary Institute: Richmond, CA.2013.
Contaminants of Emerging Concern in San Francisco Bay: A Summary of Occurrence Data and Identification of Data Gaps. SFEI Contribution No. 698. p 121.2013.
Microparticles, Microplastics, and PAHs in Bivalves in San Francisco Bay. SFEI Contribution No. 976. San Francisco Estuary Institute: Richmond, CA.2020.
California mussels (Mytilus californianus and hybrid Mytilus galloprovincialis / Mytilus trossulus) and Asian clams (Corbicula fluminea) were collected at multiple sites in San Francisco Bay. Mussels from a reference area with minimal urban influence were also deployed in cages for 90 days at multiple sites within the Bay prior to collection.Mussels from the reference time zero site, Bodega Head, had some of the lowest microparticle levels found in this study, along with resident clams from the San Joaquin and Sacramento Rivers and mussels transplanted to Pinole Point. The highest concentrations of microparticles were in mussels transplanted to Redwood Creek and Coyote Creek. The results of this study and current literature indicate that bivalves may not be good status and trends indicators of microplastic concentrations in the Bay unless the interest is in human health exposure via contaminated bivalve consumption.
Microplastic Monitoring and Science Strategy for San Francisco Bay. SFEI Contribution No. 798. San Francisco Estuary Institute: Richmond, Calif.2017.
Microplastic Strategy Update. SFEI Contribution No. 951. San Francisco Estuary Institute: Richmond, CA.2019.
Based on the detection of microplastics in San Francisco Bay surface water and Bay Area wastewater effluent in 2015, the Regional Monitoring Program for Water Quality in San Francisco Bay (RMP) convened a Microplastic Workgroup (MPWG) in 2016 to discuss the issue, identify management information needs and management questions (MQs), and prioritize studies to provide information to answer these management questions. The MPWG meets annually to review on-going microplastic projects and to conduct strategic long-term planning in response to new information in this rapidly evolving field.
In this nascent field with new findings published almost daily, the Strategy is designed to be a living document that is updated periodically. This Strategy Update includes a short summary of recent findings from the San Francisco Bay Microplastics Project - a major monitoring effort in the Bay - and an updated multi-year plan based on the newly acquired knowledge and current management needs.
Per and Polyfluoroalkyl Substances (PFAS) in San Francisco Bay: Synthesis and Strategy. SFEI Contribution No. 867. San Francisco Estuary Institute : Richmond, CA.2018.
Pharmaceuticals and Personal Care Products in Wastewater Treatment Plant Influent and Effluent and Surface Waters of Lower South San Francisco Bay. San Francisco Estuary Institute: Oakland, Ca.2009.
Polybrominated Diphenyl Ethers (PBDEs) in San Francisco Bay: A Summary of Occurrence and Trends. SFEI Contribution No. 713. San Francisco Estuary Institute: Richmond, CA. p 62.2014.
Power Analysis and Optimization of the RMP Status and Trends Program. SFEI Contribution No. 555.2008.
Sampling and Analysis Plan for Microplastic Monitoring in San Francisco Bay and Adjacent National Marine Sanctuaries. SFEI Contribution No. 819. San Francisco Estuary Institute: Richmond, CA.2017.
San Francisco Bay Triennial Bird Egg Monitoring Program for Contaminants - 2009 Data Summary. U. S. Geological Survey: Davis, CA.2009.
Sources, Pathways and Loadings Workgroup: Five-Year Workplan (2008-12). SFEI Contribution No. 567. San Francisco Estuary Institute: Oakland.2008.
Understanding Microplastic Levels, Pathways, and Transport in the San Francisco Bay Region. SFEI Contribution No. 950. San Francisco Estuary Institute: Richmond, CA.2019.
Microplastics (particles less than 5 mm) are ubiquitous and persistent pollutants in the ocean and a pervasive and preventable threat to the health of marine ecosystems. Microplastics come in a wide variety of shapes, sizes, and plastic types, each with unique physical and chemical properties and toxicological impacts. Understanding the magnitude of the microplastics problem and determining the highest priorities for mitigation require accurate measures of microplastic occurrence in the environment and identification of likely sources.
To develop critical baseline data and inform solutions, the San Francisco Estuary Institute and the 5 Gyres Institute have completed the first comprehensive regional study of microplastic pollution in a major estuary. This project supported multiple scientific components to develop improved knowledge about and characterization of microparticles and microplastics in San Francisco Bay and adjacent National Marine Sanctuaries, with the following objectives:
- Contribute to the development and standardization of sample collection and analysis methodology for microplastic transportation research.
- Determine a baseline for future monitoring of microplastics in San Francisco Bay surface water, sediment, and fish, and in ocean waters outside the Golden Gate.
- Characterize pathways by which microplastics enter the Bay, including urban stormwater and treated wastewater effluent.
- Investigate the contribution of Bay microplastics to the adjacent National Marine Sanctuaries through computer simulations.
- Communicate findings to regional stakeholders and the general public through meetings and educational materials.
- Facilitate evaluation of policy options for San Francisco Bay, with recommendations on source reduction.
This document presents the findings of this three-year project. A companion document, “San Francisco Bay Microplastics Project: Science-Supported Solutions and Policy Recommendations,” has been developed by 5 Gyres using the findings of this study (Box and Cummins, 2019).