Regional Monitoring News
Volume 3, Issue 1
Spring 1997
Contents
Mercury In the Estuary
by Rainer Hoenicke, Jay Davis, and Adrienne Yang
Mercury (or quicksilver) is a naturally occurring metal which has several
forms. It is also one of the most toxic substances, especially when combined
with other elements to produce organic mercury compounds like methylmercury.
Mercury has been found throughout the San Francisco Estuary at elevated
concentrations in water, sediment, and organisms. It is of particular
concern as a human health issue, as it accumulates in tissues and its
levels increase up the food web. For example, fish bioaccumulate mercury
of the most toxic form--monomethylmercury--and fish at the top of the
food web can harbor mercury concentrations over one million times the
mercury concentration in the water in which they swim.
As a result of the tremendous increase in mercury production and use
in this century, as well as the ease with which many forms of mercury
dissolve in water, contamination of this metal is virtually world-wide.
It travels easily through different environmental media including the
atmosphere, in a variety of chemical forms, and is toxic to humans and
other organisms in very low concentrations. California is unique in
mercury contamination because in addition to the general, industrially
related global increases, it also contains specific contamination sites.
The California Coast Range contains one of the world's great geologic
deposits of mercury. This mercury was mined intensively during the late
1800s and early 1900s primarily in support of gold mining in the Sierra
Nevada where the mercury was used in the gold extraction process. A
legacy of leaking Coast Range mercury mines and lost Sierra Nevada quicksilver
is providing a significant, ongoing burden of mercury to the Estuary
from both sides of the State (see also Estuary, Vol. 5, No. 5,
October 1996, available from the San Francisco Estuary Project (510)
286-4392).
Toxicity and Health Concerns
As mercury cycles through various forms and media, its bioavailability
(ability to contaminate organisms) and toxicity change. Toxicity heavily
depends upon the form the mercury is in. Since only 2% of the intake of
inorganic forms of mercury is estimated to be absorbed into the bloodstream,
inorganic mercury such as mercury chloride (Hg2Cl2)
is, relatively speaking, a minor health hazard and has, for a long time,
been used in medicines as a purgative and in dental fillings. Other inorganic
forms have long been known to be a health hazard. For example, mercury
nitrate, Hg(NO3)2, was used during the Industrial
Revolution to soften felt and caused twitching and dementia among hatters,
giving birth to the phrase"mad as a hatter."
"In comparison, organic mercury forms such as methylmercury (CH3Hg)
and other organo-mercury compounds are much more toxic to humans, since
over 90% of the intake of methylmercury, for example, is absorbed into
the bloodstream.
Because mercury is found throughout the environment, everyone is exposed
to low levels through inhalation, absorption, and ingestion. Long-term
exposure to low levels of metallic mercury and organic mercury affects
the nervous system. Long-term exposure to low levels of inorganic mercury
affects the kidneys. Short term exposure to higher levels of any form
of mercury can result in damage to the brain, kidneys, and fetuses.
Mercury has been found to have a harmful effect upon a wide range of
systems including the respiratory, cardiovascular, hematologic, immune,
and reproductive systems.
Where Does Mercury Come From?
Natural Sources
Since mercury occurs naturally in the environment, there is a background
concentration independent of human-related sources. Mercury can occur
naturally in a variety of forms such as Hg0 (elemental mercury),
Hg+2 (dissolved in rainwater), or as the ore cinnabar HgS,
and as an organo-metal, such as methylmercury. Through natural chemical
and biological reactions, mercury changes form, becoming alternately more
or less soluble in water, more or less toxic, and more or less biologically
available.
As with any site on Earth, there is natural mercury contamination in
San Francisco Bay. However, it is difficult to determine just what proportion
of mercury in the Bay Area is from natural sources since what is natural
varies from one part of the world to the next. Natural sources include
volcanic activity, forest fires, and oceanic releases.
Human Sources
Mercury is used in a wide range of over 2,000 manufacturing industries
and products including barometers, thermometers, mercury arc lamps, switches,
fluorescent lamps, mirrors, catalysts for the oxidation of organic compounds,
gold and silver extraction from ores, rectifiers, cathodes in electrolysis/electroanalysis,
in the generation of chlorine and caustic paper processing, batteries,
dental amalgams, as a laboratory reagent, lubricants, caulks and coatings,
in pharmaceuticals as a slimicide, in dyes, wood preservatives, floor
wax, furniture polish, fabric softeners, and chlorine bleach. Individual
industries use different forms of mercury as well.
It is estimated that the net domestic annual use of mercury was about
3,409 tons in 1986. Of this use:
- 50% to 56% was used in the electrical industry,
- 12% to 25% was used in chlor-alkali plants to generate chlorine
and caustic soda,
- 10% to 12% was used in paint manufacturing, and
- about 3% was used in the preparation of dental amalgams.
Global human-related sources include: coal-fired power plants, gasoline
and oil combustion, smelting, chlor-alkali plants, sewage treatment, and
mercury dumping from naval vessels. In the Bay Area much of the mercury
contamination is due to mining related activities.
The Mining Connection
Historically, mercury was mined intensively in the Coast Range and transported
across the Central Valley for use in Sierra Nevada placer gold mining
operations. Virtually all of the quicksilver used in these operations
was ultimately lost into Sierran watersheds. It has been estimated that,
in river drainages of the Mother Lode region alone, approximately 7,600
tons of refined quicksilver was inadvertently deposited in conjunction
with Gold Rush era mining. Additional mercury was used throughout the
gold mining belt of the northwestern and central Sierra Nevada. The majority
of Coast Range mercury mines which supplied this practice have since been
abandoned and remain unreclaimed. As a result of these two activities,
widespread mercury contamination exists today on both sides of the Central
Valley.
Recent water quality data indicate that a significant amount of mercury
from the Gold Rush era still exists in the sediment of the upper Yuba
River watershed, and the mercury is being transported into Englebright
Reservoir where it is largely trapped. Bioavailability studies show
that the reservoir is acting as an interceptor of inorganic and methylmercury.
Even though elevated levels of mercury are found in mined upstream tributaries
and within the reservoir, the organisms below the catchment consistently
show reduced mercury concentrations compared to above the reservoir.
This means that the reservoir is acting as an interceptor of bioavailable
mercury, preventing it from being transported downstream to the Estuary.
Therefore much, but not all, of the mercury remaining from historic
gold mining may be prevented from reaching the Estuary. However, in
the rivers without dams, like the Cosumnes, gold mining mercury is still
transported unimpeded to the Estuary.
Recent work also suggests that the Coast Range may be a more important
source of mercury to Central Valley Rivers and the Estuary than the
Sierra Nevada. Possibly due to the reservoir trapping effect, the export
of mercury from northwestern Sierra Nevada rivers was found to be considerably
less than that contributed from rivers in the north central and northwestern
parts of the State.
As highlighted in Estuary (Vol. 5, No. 5, October 1996), highly
elevated concentrations of mercury were observed in the Yolo Bypass
during the unusually wet spring of 1995. Cache Creek, which drains Clear
Lake, was determined to be a significant source of mercury. The areas
draining Cache Creek have many large abandoned mercury mines, and are
known to be enriched in mercury. Work by UC Davis researcher Darell
Slotton on Davis Creek, a small tributary, has documented in-stream
loads of approximately 200 kg of mercury in single wet seasons. Although
mercury from Davis Creek is currently being intercepted by the Davis
Creek Reservoir, mercury from other similar mercury mine regions remains
available for downstream transport. Follow-up studies are underway by
the Central Valley Regional Water Quality Control Board and Slotton
to determine whether mines are the main source of mercury and to determine
how the bioavailability of mercury varies throughout the watershed.
Data Trends in the Regional Monitoring Program
One of the apparently striking conclusions that can be drawn from RMP
data is the lack of bioaccumulation of mercury in the bivalves transplanted
for 90 to 100 days at various locations in the Bay for any of the three
years of the RMP analyzed so far. Bivalves generally do not accumulate
dramatically elevated mercury concentrations, and the mercury they do
contain (primarily inorganic mercury) is transferred to the consumers
of the bivalves far less efficiently than methylmercury.
Of more importance in consumption-related toxicity to humans is the
pathway of methylmercury through larger fish that feed on other fish.
Mercury bioaccumulation in these larger fish has resulted in tissue
concentrations 100,000 times higher than concentrations in adjacent
water. In 1994 a fish tissue contamination study was conducted for the
San Francisco Estuary as part of the Bay Protection and Toxic Cleanup
Program. Findings revealed tissue mercury concentrations above levels
of human health concern in several fish species analyzed. Mercury concentrations
were particularly high in the two shark species sampled. Based on the
concentrations of mercury and other contaminants measured in this study,
advisories concerning consumption of fish caught from the Bay were issued
by the California Environmental Protection Agency's Office of Environmental
Health Hazard Assessment (OEHHA) in December 1994. Adults were advised
to limit consumption of Bay sport fish to two meals per month. Pregnant
or nursing women and children under six were advised to limit consumption
to one meal per month. The advisory also states that large shark and
striped bass should not be consumed at all. It should be noted that
the advisory does not apply to salmon, anchovies, herring, and smelt
caught in the Bay.
In 1997 a follow-up to the 1994 work is being conducted as part of
the RMP. Seven species have been targeted for sampling, including striped
bass, leopard shark, California halibut, white sturgeon, white croaker,
shiner surfperch, and jacksmelt. The objectives of this sampling effort
are:
- to produce the information needed for updating human health advisories
and conducting human health risk assessments, and
- to measure contaminant levels in fish species over time to track
trends and to evaluate the effectiveness of management efforts.
This sampling will be conducted in June. In order to establish long-term
trends in concentrations, sampling for mercury and other contaminants
in fish tissue will continue to be conducted in future years. For more
information on RMP fish studies contact Jay Davis at SFEI: (510) 430-0801.
Figure 1. Mercury accumulation or depuration in three species
of transplanted bivalves for six sampling periods from 1993-1995.
Initial (T-0) concentrations are subtracted from tissue concentrations
after retrieval to give concentrations accumulated or depurated
(negative value) during deployment in the Estuary. Bars indicate
the range of values of all stations where species were deployed. |
Potential Control Measures
Control of human-related sources of mercury pollution involves both point
and area source control. Point source control is often wielded through
mechanical or chemical means, while area control is often executed by
administrative means. It is always true that it is easier to recover mercury
at the source, where it is more concentrated, than it is to recover it
after it has dispersed in different forms and species throughout the environment.
The continuous cycling of mercury through its many different forms also
complicates the job of devising effective clean-up methods.
Source Control: Mercury point source investigators have been
very effective in isolating sources in the environment. Extremely sensitive
analytical instrumentation is now available to monitor total mercury
emissions or to analyze mercury's different forms down to the picogram
(a millionth of a millionth of a gram) level. Source control includes
the remediation of abandoned mines, waste stream capture, and flue gas
scrubbing.
Area Control: Ingestion of fish and other seafood contaminated
with methylmercury is a dominant source of mercury exposure in many
parts of the United States and the world. Administrative controls to
limit the exposure of humans to mercury include warning limits on the
amount of fish consumed in a given period. Other area controls include
capping waste sites to limit exposure to the environment, specialized
dredging, and washing of mercury-contaminated soil and sediment.
The Regional Water Quality Control Board (Regional Board) has formed
a task force to take a broad view of the mercury situation in the Northern
Estuary from the Central Bay up to the Delta. The need for this pilot
project surfaced because of smaller, shallow water, North Bay dischargers
who are faced with regulation compliance problems if mercury limits
were set at the same levels for all dischargers. The goal of this project
is to find a broad range of cost-effective solutions for point and non-point
source pollution and to determine the largest source(s) of mercury.
Key questions which will be considered by the Regional Board are:
- How does mercury get transported down a watershed system and where
are the key points during the transport at which inorganic mercury
is transformed to organic mercury, which poses a risk for the Estuary?
- What is the proportion of historic mercury contamination versus
current sources?
- What is the rate at which existing sinks of mercury are moving
from the Bay to the ocean and how do current loading rates affect
this process?
- What human activities accelerate or dampen the transfer of mercury
currently found in the Bay system to more bioavailable organic forms,
and do the cumulative effects of these activities substantially increase
human health and wildlife risks?
- How do we estimate mercury loading from the atmosphere, small North
Bay watersheds, the Sacramento River, and point source discharges?
In the San Francisco Estuary, mercury contamination is probably far too
widespread for direct or physical area control measures to be effective
or economically feasible. However, significant opportunities may exist
for effective point source remediation of important mercury discharges,
which would otherwise continue to be transported into the Estuary.
Acknowledgments
This article contains excerpts from a larger paper, Mercury Effects, Sources,
and Control Measures by Alan B. Jones and Darell G. Slotton, which is
available from SFEI. Review contributions by Dr. Christopher Foe, Central
Valley Regional Water Quality Control Board, and Joseph Domagalski, United
States Geological Survey, are gratefully acknowledged. Information on
current work on mercury in the Northern Estuary was provided by Kim Taylor,
S.F.B. Regional Water Quality Control Board.
For more information on fish contamination in California, contact the
Pesticide and Environmental Toxicology Section (PETS) of OEHHA, 2151
Berkeley Way, Berkeley, CA 94704-1011, at (510) 540-3063, or the Sacramento
office, 601 North 7th Street, P.O. Box 942732, Sacramento,
CA 94234-7320, at (916) 327-7319. County departments of environmental
health may have more information on specific fishing areas.
back to contents
In Brief: 1995 RMP Results
by Adrienne Yang
The 1995 RMP Annual Report has been completed. That report includes monitoring
results from the Base Program, Pilot and Special Studies, and summary
and perspective articles contributed by RMP investigators and other scientists.
Below are a few highlights from the RMP Base Program. For the Executive
Summary and the full report please contact SFEI at (510) 430-0801 or visit
our world wide web site at: http://www.sfei.org.
Water
Dissolved trace element (i.e., metals) concentrations were generally elevated
at the Southern Slough and South Bay monitoring stations. Relative to
other Estuary reaches, most dissolved trace organics were elevated in
the South Bay with concentrations progressively decreasing from Coyote
Creek to the Golden Gate station. This pattern was repeated with dissolved
organics data adjusted for total suspended sediment, which indicated the
presence of trace organic sources in the South Bay and DDT compounds at
the Rivers station.
Clear seasonal variations were observed for arsenic, cadmium, dissolved
silver, and some trace organics. Arsenic, cadmium, and dissolved PAH
concentrations were high throughout the Estuary in August, silver concentrations
were especially elevated in the South Bay in August, and the pesticide
diazinon was highest at nearly all stations in February.
In 1995, the overall pattern of water quality exceedances was very
similar to that of 1994; concentrations of many contaminants were above
applicable water quality objectives or criteria. Of the trace elements,
copper, chromium, lead, mercury, and nickel had concentrations higher
than water quality guidelines on one or more occasions with copper,
mercury, and nickel being most frequently above guidelines in the Southern
Sloughs, South Bay, and Northern Estuary. Of the trace organic contaminants
total PCBs, total PAHs, and several individual PAHs and pesticides had
concentrations above guidelines. The stations with the largest number
of exceedances were Coyote Creek, Dumbarton Bridge, and Petaluma River.
For a summary of aquatic toxicity results, please see Trends
in Aquatic Toxicity on page 5.
Sediment
Despite 1995 being a very wet year, the distributions and concentrations
of sediment contaminants in the Estuary remained similar to those in previous
years. Average concentrations of silver, cadmium, lead, mercury, and selenium
were highest in the South Bay and Southern Sloughs, while average concentrations
of arsenic, chromium, copper, nickel, and zinc were highest in the Northern
Estuary. Trace organic contaminant concentrations in sediment were always
higher south of the Golden Gate, similar to the pattern found in water.
Probably due to the wet winter, nearly all trace metal concentrations
were higher in August than in February at the Southern Slough stations.
For trace organics, PAHs were generally highest in February in the South
and Central Bays, PCBs were highest in August in the South Bay, and
DDTs were always higher in August.
As in past years, nickel concentrations were consistently above the
Effects Range Median guideline developed by the National Oceanic and
Atmospheric Administration; however, nickel occurs naturally in the
soils of the Bay Area, and these natural sources may provide larger
inputs than human sources. Also similar to past years, arsenic, chromium,
copper, mercury, nickel, and DDTs were usually above the Effects Range
Low concentrations. Bioassays conducted over the past six years indicate
that sediment toxicity is widespread in time and space; the highest
incidence of toxicity occurred at Grizzly Bay where sediments were toxic
in 60% of test conducted between 1991 and 1996 .
Bivalves
Unlike in previous years, lead and nickel were the only trace metals that
uniformly accumulated substantially above background concentrations--lead
at all Estuary stations and nickel at all but one. Despite the unusually
high concentrations of mercury in sediment at the San Jose/Sunnyvale LEM
station in February and June, no signal from high mercury loads suspected
to have been transported into the Estuary was observable in bivalve tissue
at any of the South Bay stations. For trace organics, total PCBs were
uniformly lower in 1995 compared to 1994.
Many of the chlorinated pesticides showed distinct seasonal differences
at most stations. Elevated wet-season concentrations were observed at
Coyote Creek for DDTs, chlordane, and dieldrin, suggesting runoff as
a source.
Of the trace elements with Maximum Tissue Residue Level guidelines,
only arsenic had levels higher than guidelines; however, it should be
noted that this guideline was exceeded even at the uncontaminated control
site. Of the trace organics, only PCB and PAH levels were consistently
above guidelines throughout the Estuary. For the second year in a row,
the two sites (Coyote Creek and Petaluma) with the most elevated contaminant
concentrations in tissues also showed pronounced bivalve condition index
(a measure of bivalve health) decreases.
Trends
From 1993 to 1995 most contaminant concentrations remained constant, with
no obvious increasing or decreasing trends. Average PCB concentrations
appear to have decreased in sediments in the River and Central Bay (Figure
1), while DDTs appear to have decreased in water and sediments in
the Rivers (Figure 2), but
there were no observable differences in other reaches.
Figure 1. Plots of average PCB concentrations in sediments
in two Estuary reaches in 1993-1995. |
Figure 2. Average DDT concentrations in water at River stations
from 1993-1995. |
back to contents
Where is the RMP Going?
by Rainer Hoenicke
At the time the Regional Monitoring Program for Trace Substances was established,
the Regional Board and Program Participants agreed to build in regular
reviews that would evaluate the Program from a variety of angles. The
first of these external program reviews began this January, during the
fifth year of the RMP, and will be completed in June.
The inherent purpose of monitoring programs is to inform decision-makers
through successive measurements about what kind of change in conditions
is occurring over time. Monitoring programs are only valuable if the
scientific information is used to adjust policy, management, and individual
decisions that may have direct bearing on the status of the resource
or the system being monitored. Decision-makers can encompass managers,
regulators, scientists, and the public. Only if their needs are clearly
identified and taken into account will monitoring produce useful information.
The five-year RMP review is evaluating:
- if the objectives of the RMP are reflecting the users' expectations,
- if the scientific and technical approaches are appropriate to meet
the stated objectives, and
- if these approaches are carried out in an efficient manner.
A team has been assembled of highly respected and experienced scientists
that have expertise in the design, management, and evaluation of large-scale
monitoring and assessment programs. The review panel will evaluate administrative,
quality assurance, and statistical design questions, as well as the effectiveness
of information management and how effectively the information generated
is used by the Regional Board and Program Participants.
Core review questions fall into the components of Program Objectives,
Program Activities, Outputs, Organization, and Administration. The
review includes an assessment of how these components interact with
each other. The panelists are currently preparing their individual assessments
which will be combined into a report. After reviewing various drafts,
the RMP Steering Committee will develop a schedule for implementing
recommendations. Stay tuned for the outcome.
RMP 1997 Cruise Schedule
Water Cruise #13
Bivalve Deployment Cruise #13
Sediment Cruise #13
Water Cruise #14
Bivalve Retrieval Cruise #13
Bivalve Deployment Cruise #15
Bivalve Maintenance Cruise #15
Water Cruise #15
Sediment Cruise #15
Bivalve Retrieval Cruise #15
|
January 21-24, 27-29
January 28-30
January 30-31. February 3-5
April 14-17, 21-23
May 6-8
June 4-6
July 16-18
July 28-31, August 4-6
August 7-8, 11-13
September 2-4
|
back to contents
Annual Meeting Summary
by Rainer Hoenicke
The 3rd Annual Meeting of the Regional Monitoring Program for
Trace Substances was held on February 6 and 13, 1997, at the Samuel Merritt
College Health Education Center in Oakland. The purpose of this year's
meeting was three-fold. First, it provided an opportunity to summarize
results from the 1995 monitoring year for Program Participants and other
interested parties. Second, as part of an external Program Review, a group
of experts in monitoring design, data management, science administration,
and policy development could familiarize themselves with the Program and
talk to scientists, SFEI staff, and Program Participants contributing
to the RMP (see the article Where
is the RMP Going? on page 2). Third, the Annual Meeting served
to clarify the linkages between the scientific information that is being
collected as part of the monitoring program and the management decision-making
process.
The first of the two days focused on programmatic issues and served
as a forum for review panelists to interview managers of participating
agencies and the Regional Board to hear first-hand about the value of
the RMP, ideas on program improvements, and lessons learned since the
inception of the RMP in 1993. SFEI's Senior Scientist, Dr. Bruce Thompson,
set the stage by relating "environmental values" which are important
to society as a whole, such as fishable waters, recreational opportunities,
and preservation of threatened plant and wildlife species, to specific
environmental indicators that could tell decision-makers and the public
whether or not these values are being realized. A monitoring program
is most meaningful if it can measure some kind of response, hopefully
a positive one, to actions being undertaken to meet well-defined environmental
goals. Dr. Thompson's presentation attempted to stimulate some thought
as to whether or not the current objectives of the RMP are sufficient
to address Estuary condition in terms of pollutants and to supply environmental
managers with the right kind of information.
Subsequent speakers presented background and results related to two
RMP Pilot Studies on wetlands and watersheds. These speakers were followed
by Larry Kolb, Assistant Executive Officer of the San Francisco Bay
Regional Water Quality Control Board (Regional Board). Mr. Kolb explained
the rationale behind the Regional Board's "Watershed Management Initiative"
and the implications for effective project prioritization and resource
allocation.
With the two RMP review coordinators, Drs. Brock Bernstein and Joe
O'Connor, serving as facilitators, the afternoon session was spent interactively
between the program review panelists, RMP Participants, staff from regulatory
agencies, and members of the audience.
The second day of the Annual Meeting focused on key scientific findings
of the 1995 monitoring year, a preview of selected 1996 results, and
various perspectives on toxicity trends and of selected pollutant categories
in water, sediment, and tissue. Data presentations were followed by
examples of how RMP findings, together with other studies, are being
used in a management context, such as the development of sediment quality
guidelines, evaluation of dredged material, or in permitting waste water
discharges. Dr. Brian Cole of the United States Geological Service opened
the technical session with a recent picture of the hydrologic condition
immediately following the January floods, and general Estuary water
quality parameters that influence pollutant concentrations, such as
salinity, dissolved oxygen concentrations, and phytoplankton biomass.
Karen Taberski from the Regional Board closed the second day of the
Annual Meeting with a preview and general description of the Fish Contamination
Pilot Study which will help assess the health risk level associated
with consuming contaminated fish from the Estuary.
Both days of the Annual Meeting were well attended with 96 people attending
the first day and 140 the second. As in the previous two years, the
primary audience was the environmental management community made up
of regulatory and resource agencies, public and private dischargers
of treated waste water, storm water, dredged material, and cooling water.
The meeting also attracted a significant number of scientists and members
of public interest groups. In response to the increasing size of the
monitoring information base, an expansion of the meeting to a two-day
conference became necessary and seemed to work for most attendees. If
you have any comments about how well the Annual Meeting served your
needs, or if you have suggestions for improvements, please contact Rainer
Hoenicke at (510) 231-5731 or via e-mail at jay@sfei.org.
back to contents
Trends in Aquatic Toxicity
by Bruce Thompson, SFEI
The RMP has been conducting aquatic bioassays on ambient water samples
since the program began in 1993. Three different bioassays have been conducted
on samples collected in the wet (usually February) and dry (August) climate
periods. In 1993, the diatom Thalassiosira pseudonana and larval
bivalves (mussels or oysters) were used. Beginning in 1994, the mysid
Mysidopsis bahia was used instead of the diatom. For the mysids,
percent survival in 7 day exposures to ambient water is measured. For
the larval bivalves, percent normal development in 48 hour exposures is
measured. Toxicity is indicated when the results in the ambient water
sample are statistically lower than in a clean water control. The bioassays
have been conducted through contracts with S.R. Hansen and Associates
in Concord in 1993 and 1994, and by Pacific EcoRisk Laboratory in Martinez
beginning in 1995.
BioassayA laboratory test using live organisms to measure biological
effects of a substance, factor, or condition. |
In 1993, no toxicity was reported at any of the RMP stations in either
the diatom or larval bivalve test. Toxicity has never been observed
in the larval bivalve test at any RMP station. However, toxicity to
the mysids has been observed in 46% of the samples collected from the
Sacramento River, San Joaquin River, Grizzly Bay, and Napa River stations
(Table 1) in 1994 through
February 1997. Toxicity was less frequent in 1994 and 1995 than in 1996
and 1997. Beginning in February 1996, toxicity occurred in almost all
samples at those four stations. Toxicity was so severe at the San Joaquin
River station in February 1996 and 1997 that none of the mysids survived
the 7 day exposure. In contrast, aquatic toxicity has only occurred
in one other sample in the Estuary (Red Rock, February 1994) since testing
began in 1993.
The cause of the observed toxicity to the mysids is not clear. Because
of the location near the bayward end of large rivers, and the time of
the year (February at least) that toxicity was observed, dissolved pesticides,
particularly diazinon and chlorpyrifos, are suspected. However since
the ambient water tested usually contains numerous contaminants, it
is difficult to tell which ones may be responsible. Toxicity Identification
Evaluations (TIEs) are chemical fractionation procedures that can identify
the probable cause of toxicity. However, the RMP does not currently
conduct TIEs on toxic water samples, but should consider including them
in the future. Water chemistry data from the 1996 samples are just now
being analyzed and may shed some light on the possible causes of toxicity.
Table 1. Percent survival of mysids exposed to ambient water for
7 days at four northern RMP sites.
* indicates toxicity.
|
Sacramento River Aquatic Mysids |
San Joaquin River Aquatic Mysids |
Grizzly Bay Aquatic Mysids |
Napa River Aquatic Mysids |
Feb 94 |
95 |
73 |
90 |
63* |
Aug 94 |
95 |
93 |
90 |
93 |
Feb 95 |
93 |
83* |
98 |
88 |
Aug 95 |
93 |
95 |
90 |
88 |
Feb 96 |
7.5* |
0* |
60* |
2.5* |
Aug 96 |
75* |
73* |
73* |
88 |
Jan 97 |
22.5* |
0* |
77.5* |
72.5* |
The implications of the aquatic toxicity observed in the RMP samples
on invertebrates, fish, and birds that inhabit those areas is also poorly
understood. Some studies focused on biological effects of contaminants
in water are being developed by the Interagency Ecological Program.
The RMP also needs to pursue that question.
back to contents
|
The San Francisco Estuary Institute and
the Bay Area Regional Watershed Network
present
the 4th Annual Regional Volunteer Monitoring Conference
Launching Partnerships for Bay Area Watersheds
Saturday, September 13, 1997
at the
San Francisco Theological Seminary in San Anselmo
For more information or a registration form,
please call Andy Peri at (415) 457-0802
|
back to contents
RMP Data on the Web
by Jung Yoon and Todd Featherston
RMP data are now accessible via the WWW. The Online RMP Database was unveiled
at the Annual Meeting in February and it received many positive comments
from the participants. The Online RMP Database allows anyone with access
to the WWW to dynamically select, view, and download data using a point
and click user interface. We have completely redesigned the web page to
be more user friendly and informative; each screen now provides directions
specific to the screen and context sensitive information. Unlike the limited
demonstration version introduced last year, all published RMP data (1993
through 1995) are now accessible.
We took a "wizard" approach in designing the Online RMP Database where
a user is prompted to make one decision per screen and move on to the
next screen until all required information (data type, parameter type,
time, and location ) is provided. The information is sent to the RMP
Database at SFEI and the database returns the specific data set to the
user. The resulting output can either be viewed online in the web browser
or downloaded in ASCII format which can be loaded into any spreadsheet
application. Please read the online instructions for more detailed information.
To access RMP data, point your web browser to SFEI's home page (http://www.sfei.org)
and click on the link to Online RMP Database link. You will then be
presented with a Data
Usage and Publication Policy (see page 9). Please read the policy
and then click on Online RMP Database button to start your data request.
We welcome any suggestions and comments so please use "Click here for
Comments" button to let us know what you think.
back to contents
Data Usage and
Publication Policy
The RMP collects a large amount of data each year. Including the data
collected in the BPTCP Pilot Studies, in addition to the RMP data since
1993, the amount of information is formidable.
One of the main principles of the RMP has been to be able to obtain
and provide data in a timely manner to a variety of potential users.
The purpose of this Policy Statement is to provide some guidelines for
usage, reporting and publication of RMP data. It is not the intent of
this Policy to restrict RMP data usage or availability.
All of the RMP and BPTCP data have been obtained and analyzed using
public funds. Therefore, the data are public domain and the RMP cannot
constrain the availability or usage of the data. However, prudent usage,
knowledge of the data quality, and professional courtesy should all
be considered in obtaining and using RMP data.
Annual Report
The RMP Annual Report is the main way information from the base program
and Pilot and Special studies is collectively reported. The first obligation
of RMP investigators and participants is to provide RMP data to SFEI to
assure Annual Report publication in a timely manner.
Base Program results will generally be produced by SFEI staff. However,
some sections, or contributions to discussions may be solicited by the
Program Manager. Pilot and Special Studies summaries will usually be
written under contract by the lead investigator. Suggestions for other
contributions may be made to the Program Manager who will consider all
reasonable requests to include information. The content of the Annual
Report will be determined by the Steering Committee upon recommendation
by the Technical Review Committee.
Publications, Presentations and other Reports
There are many other opportunities to disseminate RMP results. Some formal
journal publications and technical reports have been produced from RMP
data, and several presentations at regional and national symposia have
been made by RMP participants and SFEI staff. The use of RMP data in presentations,
peer reviewed publications, or other technical reports is encouraged.
However, peer-reviewed publications using RMP data should be the privilege
of the RMP investigators. Other researchers who want to use RMP data should
extend professional courtesy to the RMP investigator(s) that produced
the data (see Table
1), which includes consideration for co-authorship or acknowledgment
on publications or reports based mostly on RMP data. It is recommended
that researchers who want to use RMP data discuss their intentions with
the RMP investigator(s) early-on in manuscript preparation. Notification
of the RMP Program Manager is also requested so that an RMP Contribution
Number can be issued (see below).
World Wide Web Access
RMP data is available on the WWW. It is anticipated that there will be
occasions where the data would be used in reports or publications by non-RMP
participants. The guidelines stated in this policy apply. A copy of this
Policy Statement is posted to all who access RMP data via the WWW.
RMP Contribution Numbers
A record of all RMP-related publications and reports will be maintained
by SFEI. All authors that publish RMP data should obtain a RMP Contribution
Number from the RMP Program Manager. Publications that use mostly RMP
data should cite a RMP Contribution Number in the Acknowledgments.
Contact
RMP Program Manager, Bruce Thompson, Ph.D., SFEI, Richmond, CA. (510)
430-0801; brucet@sfei.org.
Table 1. RMP Investigators. This list is for the RMP base program.
Principal Investigators for RMP Pilot and Special Studies are included
in the Annual Reports.
Trace Metals
Dr. Russ Flegal, UCSC
Mr. Richard Brooks, Brooks-Rand, Seattle, WA (As, Hg, Se)
Dr. Terry Wade, Texas A&M, GERG (TBT)
Trace Organics
Dr. Robert Risebrough, (1993)
Dr. Terry Wade, Texas A&M, GERG (1993-1996)
Dr. Wally Jarman, UCSC
Sediment Bioassays
Mr. John Hunt and Brian Anderson, UCSC Granite Canyon Lab
Aquatic Bioassays
Dr. Steve Hansen, SR Hansen, and Assoc. Concord (1993, 1994)
Dr. Scott Ogle, Pacific Eco-Risk, Martinez, (1995-)
Bivalve Condition and Survival
Dr. Andy Gunther, AMS, Livermore.
|
back to contents
|
SFEI Seminar Series
presents
Dr. Darell Slotton, U.C. Davis
"Mercury in Northern California: Sources, Sinks,
and Bioaccumulation"
Friday, May 23, 1997 at 11:00 a.m.
EBMUD Administration Building
375 11th Street, Oakland
in the Large Training Room on the second floor
For more information, please contact
Jay Davis at (510) 430-0801, ext. 625 or via email at jay@sfei.org
|
Newsletter Survey
Regional Monitoring News will be undergoing some changes over the next
few months. Although the focus of the newsletter will still be on the
RMP, we will be broadening our scope to include other monitoring and research
activities. Please help us in our endeavors by completing and returning
the survey below. We will use your comments and suggestions to make this
newsletter even better. Surveys should be sent to:
San Francisco Estuary Institute
1325 S. 46th Street, Bldg. 180
Richmond, CA 94704
(510) 231-9414 (FAX)
1. How often do you read the RMP News?
Always |
Most of the time |
Some of the time |
Never |
2. The articles are of interest to me....
Most of the time |
Some of the time |
Hardly ever |
Never |
3. How do you find the technical level of the articles?
Too technical |
Just Right |
Not technical enough |
4. To what audience(s) would you like to see this newsletter tailored?
(please circle all that apply)
General public |
"Involved public" |
Scientists |
Managers |
5. Are you generally satisfied with the format of the newsletter?
6. What topics would you like to see covered in future issues?
7. Would you be willing to write articles for future issues? Y N
If yes, please give us your name, contact phone number, and article
topic(s).
8. How can this newsletter be improved?
9. Do you have any suggestions for names of the revamped newsletter?
10. Additional Comments?
Name and Affiliation (optional):
Thank you for taking the time to fill out this survey.
back to contents
RMP Calendar
Thursday, May 22nd
RMP Technical Review Committee Meeting, 9:30-3:30, at SFEI offices on
the Richmond Field Station.
Friday, May 23rd
SFEI Seminar Series with Dr. Darell Slotton on "Mercury in Northern
California: Sources, Sinks, and Bioaccumulation," 11:00-12:00 at the
EBMUD Administration Building, 375 11th Street, Oakland.
Monday, June 2nd
RMP Review Workshop, 9:30-12:00, at SFEI offices on the Richmond Field
Station.
Monday, June 2nd
NORCAL SETAC, at the University of San Francisco. Information: Robert
Toia (415) 422-5927.
Monday, June 9th
RMP Steering Committee Meeting, 9:30-12:00, at SFEI offices on the Richmond
Field Station.
Monday, July 21st
RMP Steering Committee Meeting, 9:30-12:00 at SFEI offices on the Richmond
Field Station.
Announcements
1995 RMP Annual Report Available
The 1995 RMP Annual report is now available from SFEI for $25 ($15 for
non-profit organizations). Shipping and handling is included. To order,
please contact Gabriele Marek at (510) 430-0801. 1993 and 1994 Annual
Reports are also available.
RMP Contribution Numbers
SFEI has begun compiling articles and reports that have been produced
using mainly RMP data. Please help us by providing reprints and/or a list
of titles of articles or reports that you have produced using mainly RMP
data. Each document will be catalogued and assigned a RMP contribution
number. The listings of RMP contributions will help us demonstrate the
applicability and use of RMP data. For more information, please call Bruce
at (510) 231-5613.
|