Dredged Material Testing Thresholds for San Francisco Bay Area Sediments

This page presents sediment chemistry thresholds for seven different contaminant classes, used by the Dredged Material Management Office (DMMO) for determining when bioaccumulation testing will typically be required for dredged material proposed to be discharged at unconfined open water disposal sites in San Francisco Bay. These same thresholds are also used by DMMO to determine when additional analysis of the post-dredge sediment surface (“residual” or “z-layer” sediments) may be warranted. The June 9, 2011, Essential Fish Habitat Agreement between USACE, USEPA, and NMFS established the approach used to determine the testing thresholds for San Francisco Bay sediments.

The individual chemical thresholds presented in the table below are of two types:

  1. Thresholds for mercury, total PCBs, and total PAHs are based on San Francisco Bay ambient sediment concentrations determined via the Regional Monitoring Program (RMP), and are recalculated and updated each year. Similar calculations are used to update TMDL in-Bay dredged material disposal limits for mercury and total PCBs each year. (Details on how these ambient-based thresholds are calculated are provided below.)
  2. Thresholds for total DDTs, total chlordane, Dieldrin, and dioxins/furans are based on similar values in use in other parts of the country and generally remain the same year-to-year.

Dredged Material Testing Thresholds Effective in Calendar Year 2014

  Mercurya (mg/kg dw) Total PCBs (μg/kg dw) Total PAHs (μg/kg dw) Total DDTs (μg/kg dw) Total Chlordane (μg/kg dw) Dieldrin (μg/kg dw) Dioxins/ Furans (pg/g dw)
Bioaccumulation Trigger 0.33 18 4,500 50 37 1.9 10
TMDL Limit 0.470 29.6 -- -- -- -- --
Basis b b b c c d e
  1. DMMO no longer requires bioaccumulation testing for mercury above the BT. See Amendment to EFH consultation.
  2. Threshold based on San Francisco Bay ambient sediment concentrations, as describe further below.
  3. Published bioaccumulation trigger for Puget Sound marine sediments.
  4. Published marine SL value from the Pacific Northwest Sediment Evaluation Framework.
  5. Toxicity Equivalency Quotient (TEQ) based on WHO 1998 Toxicity Equivalency Factors (TEFs). Value is consistent with the published Puget Sound limit for unconfined aquatic disposal, and is ½ the established limit for placement at the Hamilton Wetlands Restoration Project site.

SUMMARY OF RMP AMBIENT SEDIMENT CALCULATIONS FOR USE IN
DREDGED MATERIAL MANAGEMENT AND TESTING

What data are used in calculating the threshold concentrations for Mercury, PCBs, and PAHs?

 

RMP sediment data collected since 2002 form the basis for calculating both the Dredged Material Management Office (DMMO) bioaccumulation testing trigger concentrations (BTs) for mercury, PCBs and PAHs, and the TMDL-based in-Bay disposal limits for mercury and PCBs. The BTs are calculated using the 90% Upper Tolerance Limit (UTL) of the 90th percentile concentrations of mercury, PCBs, and PAHs, while the TMDL-based limits for mercury and PCBs are calculated using the 90% Upper Tolerance Limit of the 99th percentile concentrations.

These values are intended to be based on the most recent 10 years of RMP sediment data. However, prior to 2002, the RMP sampling design consisted of repeated sampling of fixed stations along the spine of the Estuary. In 2002 the RMP adopted a probabilistic (random, spatially balanced) sampling design to obtain a more representative characterization of conditions throughout the Bay, and only the newer data are used in calculating the BTs and TMDL-based limits. Therefore the 2012 BTs and TMDL-based limits were based on only nine years of data (2002-2010) rather than 10 years. Since the newest 10-year data set is used to calculate each year's thresholds, the individual values are expected to change slightly each year and may be higher or lower than the previous year.

Which calendar year threshold applies for making suitability determinations?

 

The DMMO will make suitability determinations for in-Bay disposal using the BT and TMDL thresholds in effect at the time of the determination. In general, BT and TMDL thresholds in effect at the time a suitability determination is made will remain valid as long as the suitability determination holds: for example, even if the material is not dredged until a subsequent year or if the determination includes a Tier I testing exclusion for a future dredging episode. However, if conditions have changed substantially enough for the DMMO to require a new round of testing and a new suitability determination, the thresholds in effect at the time of the new suitability determination will be used.

The summary table below presents the calendar year 2014 BTs for mercury, PCBs, and PAHs and the calendar year 2014 TMDL-based in-Bay disposal limits for mercury and PCBs, after removal of any statistical outliers. Further details on the calculation of these thresholds are provided in the links below. Note: the actual BTs used by DMMO agencies are based on the 90th UTL of the 90th percentile concentrations shown, but rounded to the nearest two significant figures. Thresholds for prior years are also shown.

In order to make direct comparisons of dredging project sediment chemistry results to BTs and TMDL limits, it is important that dredgers report total PCBs (40 congeners) and total PAHs (25 compounds) in the same manner as the RMP. The target analytes are shown in this table. A discussion of DMMO’s accepted method for analyzing PCB congeners in San Francisco Bay area dredged material is presented here.

For questions, contact Beth Christian (echristian@waterboards.ca.gov; 510-622-2335).

Ambient-Based Thresholds Effective in Calendar Year 2014 (Based on 2003-2012 RMP Data)

Contaminant 90% UTL of
90th percentile
DMMO BTs 90% UTL of
99th percentile
(TMDL Disposal Limits)
Notes
Hg (mg/kg dry wt.) 0.332 0.33 0.470 Total Mercury
PCB (μg/kg dry wt.)1 18.3 18 29.6 Sum of 40 congeners2
PAH (μg/kg dry wt.) 4,511 4,500   Sum of 25 PAHs2

 

1 The ambient-based thresholds for PCBs are based on 2002-2003 and 2007-2012 RMP data. The 2004-2006 PCB data are not included in the analysis because of a recently identified issue with sample processing at the laboratory. PCB results for 2004-2006 passed routine laboratory and RMP Quality Assurance; however, were censored in 2014 due to a low bias identified in the extraction method. The 2002-2003 samples were re-analyzed alongside the 2010 samples; therefore, the 2002-2003 data are unaffected. 

2The RMP reports total PCBs and PAHs using slightly different analyte lists and/or analytical methods than those shown in the DMMO's “Guidelines for Implementing the Inland Testing Manual in the San Francisco Bay Region”. For PCBs, instead of the Aroclor mixtures, the RMP reports a sum of 40 PCB congeners. For dredged material testing, the DMMO recommends USEPA Method 8082 which employs gas chromatography/electron-capture detection (GC/ECD) capable of achieving per congener detection limits in the 0.1 – 0.6 μg/kg range and reporting limits in the 0.5 – 1.0 μg/kg range. Alternative analytical methods may be acceptable as long as the detection and reporting limits are comparable to those of Method 8082. For PAHs, the RMP reports a slightly expanded list of PAH compounds (25 compounds vs. the previous DMMO list of 16). Since all the PAHs in this expanded list are measured by the same analytical method most commercial laboratories already use when analyzing sediment samples (EPA 8270 SIM), there should be little or no cost increase for reporting the additional PAHs.

Ambient-Based Thresholds from Prior Years

Ambient-Based Thresholds Effective in Calendar Year 2013 (Based on 2002-2011 RMP Data)

Contaminant 90% UTL of
90th percentile
DMMO BTs 90% UTL of
99th percentile
(TMDL Disposal Limits)
Notes
Hg (mg/kg dry wt.) 0.336 0.34 0.469 Total Mercury
PCB (μg/kg dry wt.) 17.4 17 28.7 Sum of 40 congeners2
PAH (μg/kg dry wt.) 4,446 4,400   Sum of 25 PAHs2

 

2The RMP reports total PCBs and PAHs using slightly different analyte lists and/or analytical methods than those shown in the DMMO's “Guidelines for Implementing the Inland Testing Manual in the San Francisco Bay Region”. For PCBs, instead of the Aroclor mixtures, the RMP reports a sum of 40 PCB congeners. For dredged material testing, the DMMO recommends USEPA Method 8082 which employs gas chromatography/electron-capture detection (GC/ECD) capable of achieving per congener detection limits in the 0.1 – 0.6 μg/kg range and reporting limits in the 0.5 – 1.0 μg/kg range. Alternative analytical methods may be acceptable as long as the detection and reporting limits are comparable to those of Method 8082. For PAHs, the RMP reports a slightly expanded list of PAH compounds (25 compounds vs. the previous DMMO list of 16). Since all the PAHs in this expanded list are measured by the same analytical method most commercial laboratories already use when analyzing sediment samples (EPA 8270 SIM), there should be little or no cost increase for reporting the additional PAHs.